Citric acid production by electrodialysis with bipolar membranes

نویسنده

  • Xu Tongwen
چکیده

Production of citric acid from sodium citrate was carried out by electrodialysis (ED), using bipolar membranes (BP) prepared from poly(phenylene oxide) (PPO). The process feasibility was tested using a laboratory ED-cell with an effective area 20 cm. Based on the configuration of BP-cation membranes (C)-BP, the performances of various sodium sulfate concentrations and sodium citrate concentrations are compared and discussed in terms of ionic transport and ion exchange. It is suggested that, in such an operation, the optimum concentration range be 0.5–1.0 M for sodium citrate and 0.25–1.5 M for sodium sulfate from the viewpoint of energy consumption, current efficiency and acid concentration. © 2002 Elsevier Science B.V. All rights reserved.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Monopolar and Platinum Interfaced Bipolar Membrane Electrodialysis: Experimental Assessment Using Synthetic Salt Solution Heterogeneous Cation Exchange Membranes

In this study, polystyrene ethylene butylene polystyrene (PSEBS) was functionalized to prepare mono and bipolar ion exchange membranes. In the case of the bipolar membrane, platinum was used as the intermediate layer. NaCl solution of concentration ranging from 5 g/L to 25 g/L was used as the feed solution. A commercially procured ion exchange membrane made of polystyrene divinyl benzene was al...

متن کامل

In situ ion substitution of sodium gluconate: Comparison of bipolar membrane electrodialysis and electro-membrane reactor for producing gluconic acid

Based on the home-made cation-exchange membrane (CEM) and bipolar membrane (BPM), electrodialysis with bipolar membrane (EDBPM) and electro-membrane reactor with three compartments (EMR-3) were developed to achieve in situ ion substitution and recovery of gluconic acid (GLH) from its sodium salt. Physicochemical and electrochemical properties of CEM and BPM were studied to assess their...

متن کامل

Electromembrane Processes in Environment Protection

The separation membrane techniques in which an external electric field is applied as a driving force (such as electrodialysis, electro-electrodialysis, and membrane electrolysis) are shortly described and their application in environment protection is presented. Attention was focused on recovery of valuable chemicals from effluents and waste gases. Examples of new production methods that elimin...

متن کامل

Sulfuric Acid and Ammonia Generation by Bipolar Membranes Electrodialysis: Transport Rate Model for Ion and Water Through Anion Exchange Membrane

Regeneration of sulfuric acid and ammonia from ammonium sulfate by bipolar membrane electrodialysis (BMED) coupling with stripping ammonia by air-blowing was studied. The result showed that it was feasible to regenerate sulfuric acid and ammonia from ammonium sulfate solution using this method. Empirical models to describe the ion and water transport behaviors through anion exchange membrane fo...

متن کامل

Demineralization of Cheese Whey by Sequential Nanofltration (NF) and Electrodialysis (ED) Processes

In this study, demineralization of cheese whey by sequential nanofltration (NF) and electrodialysis (ED) methods was investigated. For the NF step, two NF membranes labeled as NF-270 and NF-90 were tested. Approximately 90% of protein and lactose rejections were obtained with partial demineralization during NF step. For full demineralization of the NF permeate, NF follo...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2001